AI Article Synopsis
- A polymeric cadmium(II) complex has been created using a Schiff base ligand, which involves a specialized chemical structure due to the presence of phenolato and azido groups.
- The characterization methods used include elemental analysis, infrared spectroscopy, and single crystal X-ray diffraction, confirming the complexity and coordination of the compound.
- The cadmium atoms are arranged in an octahedral geometry and are linked in pairs by phenolato groups, with further connections via azido bridges, resulting in a two-dimensional sheet structure.
Article Abstract
A rarely seen phenolato and azido-bridged polymeric cadmium(II) complex derived from the Schiff base ligand 2-bromo-6-[(2-isopropylaminoethylimino)methyl]phenol (HL) has been prepared and characterized by elemental analysis, IR spectroscopy, and single crystal X-ray diffraction. The Schiff base ligand coordinates to the Cd atom through the NNO donor set. The Cd atom is hexa-coordinated in an octahedral geometry. Adjacent two Cd atoms are bridged by two phenolato groups generating a dimer with Cd···Cd distance of 3.475(1) Å. The dimers are further linked via azido bridges forming 2D sheets parallel to the bc plane.
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| http://dx.doi.org/10.17344/acsi.2016.3036 | DOI Listing |
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