Surface modification of SiO coated ZnO nanoparticles for multifunctional cotton fabrics.

J Colloid Interface Sci

National Research Centre (Scopus Affiliation ID 60014618), Textile Research Division, Pre-treatment and Finishing of Cellulosic Fibers Department, El-Behouth St. (former El-Tahrir Str.), Dokki, P.O. 12622, Giza, Egypt.

Published: July 2017

A simple chemical synthetic route was designed to prepare zinc oxide nanoparticles (ZnO-NPs) by using sodium alginate as anti-agglomeration agent in the presence of sodium hydroxide as alkali. Next, surface modification of ZnO-NPs with SiO nanoparticles was achieved as per to sol-gel process. Further enhancing of the multifunctional properties of SiO@ZnO-NPs was conducted successfully thanks to (aminopropyl)triethoxysilan (APTES) and vinyltriethoxysilan (VTES) which, in turns, increase the affinity of the SiO@ZnO-NPs nanocomposite towards glycosidic chains of cotton fabrics. Thorough characterizations of synthesized ZnO-NPs, SiO@ZnO-NPs, SiO@ZnO-NPs/APTES and SiO@ZnO-NPs/VTES were conducted by the making use of well advanced techniques such as FT-IR, XRD, TEM, DLS and SEM-EDX. The data obtained clarified the formation of an interfacial chemical bond between ZnO and SiO as affirmed by FT-IR and XRD analysis. In addition, the results revealed by TEM, zeta sizer and SEM-EDX techniques, declared that the amorphous layers of SiO, APTES or VTES evenly coated the surface of ZnO-NPs. For these nanocomposites, the work was extended to render cotton fabrics multifunctional properties such as antibacterial and UV protection with high durability even after 20 washing cycles using pad dry cure method. Taking the advantages of the silane compounds terminated by active groups such as OH, NH, etc., open the door for further functionalization of the cotton fabrics' surfaces by durable multifunctional agents applied in various applications.

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http://dx.doi.org/10.1016/j.jcis.2017.03.080DOI Listing

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