We report the fabrication of near-vertically elongated GaN nanorods on quartz substrates. To control the preferred orientation and length of individual GaN nanorods, we combined molecular beam epitaxy (MBE) with pulsed-mode metal-organic chemical vapor deposition (MOCVD). The MBE-grown buffer layer was composed of GaN nanograins exhibiting an ordered surface and preferred orientation along the surface normal direction. Position-controlled growth of the GaN nanorods was achieved by selective-area growth using MOCVD. Simultaneously, the GaN nanorods were elongated by the pulsed-mode growth. The microstructural and optical properties of both GaN nanorods and InGaN/GaN core-shell nanorods were then investigated. The nanorods were highly crystalline and the core-shell structures exhibited optical emission properties, indicating the feasibility of fabricating III-nitride nano-optoelectronic devices on amorphous substrates.
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http://dx.doi.org/10.1038/srep45345 | DOI Listing |
J Hazard Mater
November 2024
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta T6G 1H9, Canada.
Developing a feasible and efficient membrane for the purification of surfactant-stabilized emulsions is urgently needed but impeded by the issues of membrane fouling and the inherent trade-off between separation efficiency and permeation flux. A superhydrophilic conductive membrane was developed by coating MXene/carbon nanotubes layer and polydopamine-hydrogel molecular layer, which as cathode integrates feasible hydroxide ion-assisted bubbles on its surface by electrolysis of water. These bubbles are more effective than conventional ones in removing surfactant-stabilized oil droplets because the hydroxide ions significantly promote the aggregation of oil droplets and bubbles by reducing their Debye length.
View Article and Find Full Text PDFPhys Chem Chem Phys
December 2024
School of Civil Engineering and Transportation, South China University of Technology, Guangzhou, 510640, People's Republic of China.
Due to the multi-factor coupling effect, the rule of interlayer friction in low-dimensional homogeneous thin-wall shell structures is still unclear. Double walled carbon nanotubes (DWCNTs) having a typical low-dimensional homogeneous thin-wall shell structure are selected for this study. The interlayer friction of numerous chiral DWCNTs is investigated using molecular dynamics simulations to systematically analyze and understand the coupling mechanisms of various factors in interlayer friction.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
Department of Chemistry and BINA-BIU Center for Nanotechnology and Advanced Materials, Bar-Ilan University, Ramat-Gan, 5290002, Israel (R. R. K.) (M. N.
Rechargeable Zn-air batteries (ZABs) with near-neutral electrolytes hold promise as cheap, safe and sustainable devices, but they suffer from slow charge kinetics and remain poorly studied. Here we reveal a charge storage mechanism of near-neutral Zn-air batteries that is mediated by formation of dissolved hydrogen peroxide upon cell discharge and its oxidation upon charge. This HO-mediated pathway facilitates oxygen evolution reaction (OER) at ~1.
View Article and Find Full Text PDFNanomicro Lett
November 2024
State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou, 510640, People's Republic of China.
van der Waals (vdW) heterostructures constructed by low-dimensional (0D, 1D, and 2D) materials are emerging as one of the most appealing systems in next-generation flexible photodetection. Currently, hand-stacked vdW-type photodetectors are not compatible with large-area-array fabrication and show unimpressive performance in self-powered mode. Herein, vertical 1D GaN nanorods arrays (NRAs)/2D MoS/PEDOT:PSS in wafer scale have been proposed for self-powered flexible photodetectors arrays firstly.
View Article and Find Full Text PDFThe near-field photoacoustics of gold nanoparticle in water has received much attention for its biomedical applications and is strongly affected by the gold-water interfacial thermal resistance. However, the effect of interfacial thermal resistance on near-field photoacoustics has been very little studied. Here we present the numerical simulations of near-field photoacoustic signal generation from a single gold nanorod in water by considering different thermal resistances at the gold-water interface.
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