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Atomically precise organomimetic cluster nanomolecules assembled via perfluoroaryl-thiol SAr chemistry.
Nat Chem
April 2017
Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095, USA.
The majority of biomolecules are intrinsically atomically precise, an important characteristic that enables rational engineering of their recognition and binding properties. However, imparting a similar precision to hybrid nanoparticles has been challenging because of the inherent limitations of existing chemical methods and building blocks. Here we report a new approach to form atomically precise and highly tunable hybrid nanomolecules with well-defined three-dimensionality.
View Article and Find Full Text PDFOrganomimetic clusters: Precision in 3D.
Nat Chem
March 2017
Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA.
New ligand platforms featuring boron-rich clusters as organomimetic substituents.
Pure Appl Chem
May 2013
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA, USA.
200 years of research with carbon-rich molecules have shaped the development of modern chemistry. Research pertaining to the chemistry of boron-rich species has historically trailed behind its more distinguished neighbor (carbon) in the periodic table. Notably, a potentially rich and, in many cases, unmatched field of coordination chemistry using boronrich clusters remains fundamentally underdeveloped.
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