The Influence of New Hydrophobic Silica Nanoparticles on the Surface Properties of the Films Obtained from Bilayer Hybrids.

Ultra-hydrophobic bilayer coatings on a glass surface were fabricated by sol-gel process using hexadecyltrimethoxysilane (CTMS) and tetramethoxysilane (TMOS) (1:4 molar ratio) as precursors. After coating, silica nanoparticles (SiO₂ NPs) functionalized with different mono-alkoxy derivatives (methoxytrimethylsilane, TMeMS; ethoxydimethylvinylsilane, DMeVES; ethoxydimethylphenylsilane, DMePhES; and methoxydimethyloctylsilane, DMeC₈MS) were added, assuring the microscale roughness on the glass surface. Influences of the functionalized SiO₂ NPs and surface morphology on the hydrophobicity of the hybrid films were discussed. The successful functionalization of SiO₂ NPs with hydrophobic alkyl groups were confirmed by Fourier transform infrared spectroscopy (FTIR). The thermal stability of hydrophobic SiO₂ NPs showed that the degradation of the alkyl groups takes place in the 200-400 °C range. Bilayer coating with CTMS/TMOS and SiO₂ NPs modified with alkoxysilane substituted with C₈ alkyl chain (SiO₂ NP-C₈) has micro/nano structure. Hydrophobicity of functionalized SiO₂ NPs-C₈ and its higher degree of nanometer-scale roughness gave rise to ultra-hydrophobicity performance for bilayer coating CTMS/TMOS + SiO₂ NPs-C₈ (145°), compared to other similar hybrid structures. Our synthesis method for the functionalization of SiO₂ NPs is useful for the modification of surface polarity and roughness.