AI Article Synopsis
- This study investigates how the collision-induced dissociation (CID) of proton-bound complexes of tryptophan and 2-butanol varies based on their stereo arrangement.
- The researchers measured how dissociation efficiency changes with collision energy in a single collision setting.
- Results indicate that homochiral complexes are less stable during CID compared to heterochiral complexes, supported by further measurements on diastereomeric complexes.
Article Abstract
In this work we report the stereo-dependent collision-induced dissociation (CID) of proton-bound complexes of tryptophan and 2-butanol. The dissociation efficiency was measured as a function of collision energy in single collision mode. The homochiral complex was found to be less stable against CID than a heterochiral one. Additional gas dependence measurements were performed with diastereomeric complexes that confirm the findings.
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| http://dx.doi.org/10.1002/chir.22679 | DOI Listing |
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