A metal-free photo-oxidative intermolecular C-H/C-H coupling reaction of thiophenes is demonstrated with carbonyls using a catalytic amount of molecular iodine. In this system, molecular oxygen in the air acted as a terminal oxidant to regenerate molecular iodine. A mechanistic study was also performed.
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View Article and Find Full Text PDFIodine Deficiency Hypothyroidism Among Children in the United States - 21st Century Resurgence?
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Warren Alpert Medical School of Brown University, Providence, Rhode Island.
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