LaNiO (LNO) thin films of 14 nm and 35 nm thicknesses grown epitaxially on LaAlO (LAO) and (LaAlO)(SrTaAlO) (LSAT) substrates are studied using High Resolution Transmission Electron Microscopy (HRTEM) and High Angle Annular Dark Field (HAADF) imaging. The strain state of the films is studied using Geometric Phase Analysis (GPA). Results show the successful in-plane adaptation of the films to the substrates, both in the compressive (LAO) and tensile (LSAT) cases. Through the systematic analysis of HRTEM superstructure contrast modulation along different crystal orientations, localized regions of the monoclinic LaNiO phase are detected in the 35 nm films.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1039/c7cp00902j | DOI Listing |
CrystEngComm
September 2021
Institute of Physical Chemistry, University of Innsbruck Innrain 52c A-6020 Innsbruck Austria +4351250758003.
The present Highlight article shows the importance of the monitoring of bulk crystalline compounds for a more thorough understanding of heterogeneous catalysts at the intersection of catalysis, materials science, crystallography and inorganic chemistry. Although catalytic action is widely regarded as a purely surface-bound phenomenon, there is increasing evidence that bulk processes can detrimentally or beneficially influence the catalytic properties of various material classes. Such bulk processes include polymorphic transformations, formation of oxygen-deficient structures, transient phases and the formation of a metal-oxide composite.
View Article and Find Full Text PDFNanomaterials (Basel)
December 2019
School of Physics Optoelectric Engineering, Guangdong University of Technology, Guangzhou Higher Education Mega Center, Guangzhou 510006, China.
Double perovskite BiNiMnO (BNMO) thin films grown on p-Si (100) substrates with LaNiO (LNO) buffer layers were fabricated using chemical solution deposition. The crystal structure, surface topography, surface chemical state, ferroelectric, and current-voltage characteristics of BNMO thin films were investigated. The results show that the nanocrystalline BNMO thin films on p-Si substrates without and with LNO buffer layer are monoclinic phase, which have antiferroelectric-like properties.
View Article and Find Full Text PDFPhys Chem Chem Phys
March 2017
Laboratory of Electron Nanoscopy (LENS-MIND-IN2UB), Institute of Nanoscience and Nanotechnology, Electronics Department, University of Barcelona, c/ Martí i Franqués 1, Barcelona 08028, Catalonia, Spain.
LaNiO (LNO) thin films of 14 nm and 35 nm thicknesses grown epitaxially on LaAlO (LAO) and (LaAlO)(SrTaAlO) (LSAT) substrates are studied using High Resolution Transmission Electron Microscopy (HRTEM) and High Angle Annular Dark Field (HAADF) imaging. The strain state of the films is studied using Geometric Phase Analysis (GPA). Results show the successful in-plane adaptation of the films to the substrates, both in the compressive (LAO) and tensile (LSAT) cases.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!