Evidence of a minority monoclinic LaNiO phase in lanthanum nickelate thin films.

Phys Chem Chem Phys

Laboratory of Electron Nanoscopy (LENS-MIND-IN2UB), Institute of Nanoscience and Nanotechnology, Electronics Department, University of Barcelona, c/ Martí i Franqués 1, Barcelona 08028, Catalonia, Spain.

Published: March 2017

LaNiO (LNO) thin films of 14 nm and 35 nm thicknesses grown epitaxially on LaAlO (LAO) and (LaAlO)(SrTaAlO) (LSAT) substrates are studied using High Resolution Transmission Electron Microscopy (HRTEM) and High Angle Annular Dark Field (HAADF) imaging. The strain state of the films is studied using Geometric Phase Analysis (GPA). Results show the successful in-plane adaptation of the films to the substrates, both in the compressive (LAO) and tensile (LSAT) cases. Through the systematic analysis of HRTEM superstructure contrast modulation along different crystal orientations, localized regions of the monoclinic LaNiO phase are detected in the 35 nm films.

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http://dx.doi.org/10.1039/c7cp00902jDOI Listing

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Evidence of a minority monoclinic LaNiO phase in lanthanum nickelate thin films.

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View Article and Find Full Text PDF

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