Bis(μ--methyl--phenyl-dithio-carbamato)-κ,':;κ:,'-bis-[(-methyl--phenyl-dithio-carbamato-κ,')cadmium]: crystal structure and Hirshfeld surface analysis.

Acta Crystallogr E Crystallogr Commun

Research Centre for Crystalline Materials, School of Science and Technology, Sunway University, 47500 Bandar Sunway, Selangor Darul Ehsan, Malaysia.

Published: March 2017

The title compound, [Cd(CHNS)], is a centrosymmetric dimer with both chelating and μ-tridentate di-thio-carbamate ligands. The resulting S donor set defines a Cd coordination geometry inter-mediate between square-pyramidal and trigonal-bipyramidal, but tending towards the former. The packing features C-H⋯S and C-H⋯π inter-actions, which generate a three-dimensional network. The influence of these inter-actions, along with intra-dimer π-π inter-actions between chelate rings, has been investigated by an analysis of the Hirshfeld surface.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347070PMC
http://dx.doi.org/10.1107/S2056989017002705DOI Listing

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