Crystal structure of erioflorin isolated from (L.).

Acta Crystallogr E Crystallogr Commun

Universität Potsdam, Institut für Chemie, Anorganische Chemie, Karl-Liebknecht-Strasse 24-25, D-14476 Potsdam, Germany.

Published: March 2017

The title compound, erioflorin, CHO [systematic name: (1a,3,4,5a,8a,9,10a)-1a,2,3,5a,7,8,8a,9,10,10a-deca-hydro-3-hy-droxy-4,10a-dimethyl-8-methyl-idene-7-oxooxireno[5,6]cyclo-deca-[1,2-]furan-9-yl methacrylate], is a tricyclic germacrane sesquiterpene lactone, which was isolated from (L.). The compound crystallizes in the space group 222, and its mol-ecular structure consists of a methacrylic ester of a ten-membered ring sesquiterpenoid annelated with an epoxide and a butyrolactone. The structure is stabilized by one intramolecular C-H⋯O hydrogen bond. An O-H⋯O hydrogen bond and further C-H⋯O interactions can be observed in the packing.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347047PMC
http://dx.doi.org/10.1107/S2056989017001700DOI Listing

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