This paper reviews the primary literature reporting the use of ionic liquids (ILs) in optical sensing technologies. The optical chemical sensors that have been developed with the assistance of ILs are classified according to the type of resultant material. Key aspects of applying ILs in such sensors are revealed and discussed. They include using ILs as solvents for the synthesis of sensor matrix materials; additives in polymer matrices; matrix materials; modifiers of the surfaces; and multifunctional sensor components. The operational principles, design, texture, and analytical characteristics of the offered sensors for determining CO, O, metal ions, CN, and various organic compounds are critically discussed. The key advantages and disadvantages of using ILs in optical sensing technologies are defined. Finally, the applicability of the described materials for chemical analysis is evaluated, and possibilities for their further modernization are outlined.
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http://dx.doi.org/10.2116/analsci.33.261 | DOI Listing |
Chem Commun (Camb)
January 2025
School of Chemistry, Trinity Biomedical Sciences Institute, Trinity College Dublin, 152-160 Pearse St., Dublin 2, Ireland.
Novel ionic liquid catalysts comprising terephthalate anions are capable of promoting the neutral hydrolysis of relatively large flake sizes of poly(ethylene terephthalate) at 0.5 mol% loading (200 °C, 4 h, 94% yield) without either attendant product inhibition or product contamination by protonated catalyst. Catalysts with large, lipophilic phosphonium cations outperform more polar variants.
View Article and Find Full Text PDFAnal Chim Acta
February 2025
Department of Chemistry, Iowa State University, Ames, IA, 50011, USA. Electronic address:
Background: Infections from the hepatitis B virus (HBV) are a major risk factor for hepatocellular carcinoma, one of the most common types of liver cancer. Circulating cell-free DNA (ccfDNA) in human plasma can be used as a non-invasive biomarker for diagnosing HBV-related liver diseases. The isolation of target ccfDNA sequences is often challenging due to the co-extraction of highly abundant non-target DNA from samples.
View Article and Find Full Text PDFLangmuir
January 2025
A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071 Moscow, Russia.
The results of an investigation of an impact of the structure of recently synthesized bis(trifluoromethylsulfonyl)imide mono- and dicationic ionic liquids on their properties and behavior as lubricants for slippery liquid infused superhydrophobic coatings are presented for a wide temperature range. In this study, a new approach based on monitoring the surface tension of a liquid sessile droplet on top of a coating was exploited for the analysis of the evolution of the coating properties in prolonged contact with the liquid. It was found that the continuous contact with water flow results in slippery property degradation according to two different scenarios.
View Article and Find Full Text PDFBull Environ Contam Toxicol
January 2025
College of Environmental Science and Engineering, Donghua University, Shanghai, 201620, China.
Ionic liquids (ILs) are widely used "green solvent" as they have a low vapor pressure and can replace volatile solvents in industry. However, ILs are difficult to biodegrade and are potentially harmful to the environment. This study, herein, investigated the toxicity of three imidazole ILs ([CMIM]Cl, [CMIM]Br, and [CDMIM]Br) towards soil microorganisms.
View Article and Find Full Text PDFACS Omega
January 2025
Instituto de Tecnologia Química e Biológica António Xavier, Universidade Nova de Lisboa (ITQB NOVA), Av. da República, 2780-157, Oeiras, Portugal.
Sporopollenin is a plant polymer present in the exine of the pollen grains that comprises two layers: the endexine and the ektexine. It possesses remarkable mechanical, thermal, and chemical stability and is also highly recalcitrant to hydrolysis. The chemical backbone of sporopollenin mostly consists of a polyhydroxylated aliphatic component and polyketide-derived aliphatic α-pyrone elements.
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