A simple and convenient means of fabricating concave microlens arrays direct on silica glass by using the local fictive temperature modification of fused silica is presented. This method is based on the fact that an increased fictive temperature results in a much higher HF acid etching rate of fused silica. Combining the abrupt local fictive temperature enhancement by the CO laser pulse and the subsequent etching by the HF acid solution, concave microlens arrays with high fill factors, excellent smoothness, and optical performance are generated on fused silica.
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http://dx.doi.org/10.1364/OL.42.001093 | DOI Listing |
J Chem Phys
October 2024
Department of Chemistry, The George Washington University, Washington, District of Columbia 20052, USA.
Chemical and physical processes on the surfaces of amorphous solids have been the focus of many studies over the past decades. These studies have established that dynamics in a thin layer near a glass surface are often dramatically faster than those in the glass bulk. Nevertheless, recent advances also emphasize the need for new experimental techniques capable of characterizing the structure and dynamics of the near-surface regions in glassy materials at the molecular length scale.
View Article and Find Full Text PDFJ Chem Phys
May 2024
Department of Materials Science and Engineering, University of Arizona, Tucson, Arizona 85712, USA.
Dynamic heterogeneity is a fundamental characteristic of glasses and undercooled liquids. The heterogeneous nature causes some of the key features of systems' dynamics such as the temperature dependence of nonexponentiality and spatial enthalpy fluctuations. Commonly used phenomenological models such as Tool-Narayanaswamy-Moynihan (TNM) and Kovacs-Aklonis-Hutchinson-Ramos fail to fully capture this phenomenon.
View Article and Find Full Text PDFJ Phys Chem Lett
March 2024
SPEC, CEA, CNRS, Université Paris-Saclay, CEA Saclay Bat 772, 91191 Cedex Gif-sur-Yvette, France.
We studied the physical aging of glycerol in response to upward temperature steps of amplitude ranging from 0.3 to 18 K. This was done using a specially designed experimental setup allowing quick heating of a liquid film while measuring the evolution of its dielectric properties.
View Article and Find Full Text PDFJ Chem Phys
January 2024
Department of Chemistry, University of Wisconsin-Madison, Madison, Wisconsin 53706, USA.
Glassy films of methyl-m-toluate have been vapor deposited onto a substrate equipped with interdigitated electrodes, facilitating in situ dielectric relaxation measurements during and after deposition. Samples of 200 nm thickness have been deposited at rates of 0.1 nm/s at a variety of deposition temperatures between 40 K and Tg = 170 K.
View Article and Find Full Text PDFJ Chem Phys
January 2024
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
To elucidate the atomistic origin of volume relaxation in soda-lime silicate glass annealed below the glass transition temperature (Tg), the experimental and calculated Raman spectra were compared. By decomposing the calculated Raman spectra into specific groups of atoms, the Raman peaks at 800, 950, 1050, 1100, and 1150 cm-1 were attributed to oxygen and silicon in Si-O-Si, non-bridging oxygen in the Q2 unit, bridging oxygen in low-angle Si-O-Si, non-bridging oxygen in the Q4 unit, and bridging oxygen in high-angle Si-O-Si, respectively. Based on these attributions, we found that by decreasing the fictive temperature by annealing below Tg - 70 K, a homogenization reaction Q2 + Q4 → 2Q3 and an increase in average Si-O-Si angle occurred simultaneously.
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