Tuning Sn-Catalysis for Electrochemical Reduction of CO to CO via the Core/Shell Cu/SnO Structure.

Tin (Sn) is known to be a good catalyst for electrochemical reduction of CO to formate in 0.5 M KHCO. But when a thin layer of SnO is coated over Cu nanoparticles, the reduction becomes Sn-thickness dependent: the thicker (1.8 nm) shell shows Sn-like activity to generate formate whereas the thinner (0.8 nm) shell is selective to the formation of CO with the conversion Faradaic efficiency (FE) reaching 93% at -0.7 V (vs reversible hydrogen electrode (RHE)). Theoretical calculations suggest that the 0.8 nm SnO shell likely alloys with trace of Cu, causing the SnO lattice to be uniaxially compressed and favors the production of CO over formate. The report demonstrates a new strategy to tune NP catalyst selectivity for the electrochemical reduction of CO via the tunable core/shell structure.