Imidaclopride is an insecticide widely used for pest control in agriculture around the world. It acts on the central nervous system of insects, while posing lower toxicity to mammals. This is an organic material made of Pyridinium, Dihydroimidazol and Nitramide. This structure poses a threat to the environment and humans. Until now, different types of methods have been used for elimination of this organic pollution. Recently, advanced oxidation processes (AOPs) are presented as a proposed method to remove this organic pollution. Photocatalytic degradation is also used as an efficient method for destruction of organic structures. In this study, the effect of titanium dioxide (TiO) nanoparticle as a photocatalyst activated by UV irradiation is investigated. The new design of the reactor was prepared with coaxial cylinders in which the inner cylinder is rotated at a constant speed. The reactor worked in two batch and continuous modes. The results show that the UV irradiation is more effective than activated TiO nanoparticle, as the designed reactor with UV irradiation eliminated Imidaclopride in less than 2 hours.
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http://dx.doi.org/10.1080/09593330.2017.1306115 | DOI Listing |
ChemistryOpen
January 2025
Facultad de Ciencias Básicas, Universidad de Medellín, 050026, Medellín, Colombia.
Conversion of glycerol to added-value products is desirable due to its surplus during biodiesel synthesis. TiO has been the most explored catalyst. We performed a systematic study of glycerol adsorption on anatase (101), anatase (001), and rutile (110) TiO at the Density Functional Theory level.
View Article and Find Full Text PDFNat Commun
January 2025
Department of Chemical and Environmental Engineering, Yale University, New Haven, CT, USA.
Discharge of wastewater containing nitrate (NO) disrupts aquatic ecosystems even at low concentrations. However, selective and rapid reduction of NO at low concentration to dinitrogen (N) is technically challenging. Here, we present an electrified membrane (EM) loaded with Sn pair-atom catalysts for highly efficient NO reduction to N in a single-pass electrofiltration.
View Article and Find Full Text PDFPoult Sci
January 2025
Department of Animal Science, University of Zabol, Zabol 98661-5538, Iran. Electronic address:
Calcium (Ca) is necessary for bone health and metabolic functions in poultry, however, the extent to which it can be utilized varies among feed ingredients. The goal of this study was to determine the apparent ileal digestibility (AID) and standardized ileal digestibility (SID) of calcium in wheat and soybean meal (SBM) in young quail chicks using a direct method. Three dietary treatments were used in the experiment: a calcium-free basal diet to determine endogenous calcium losses, and two diets with either wheat or SBM as the primary calcium sources.
View Article and Find Full Text PDFJ Environ Sci Health B
January 2025
Faculty of Food Technology, University of Economics-Technology for Industries (UNETI), Hanoi, Vietnam.
Antibiotic residues have become serious health concerns due to the development of antibiotic-resistant bacteria. The treatment of antibiotic pollutants in wastewater is necessary for reducing the issue of antibiotic resistance. In this work, the metal oxide photocatalyst titanium dioxide (TiO) was evaluated for the removal of the tetracycline antibiotic (TC-A) and the deactivation of bacteria (E-B) from wastewater.
View Article and Find Full Text PDFFront Mol Biosci
January 2025
Department of Agricultural and Food Sciences (DISTAL), University of Bologna, Cesena, Italy.
Introduction: Current intestinal models lack the mechanical forces present in the physiological environment, limiting their reliability for nanotoxicology studies. Here, we developed an enhanced Caco-2/HT29-MTX-E12 co-culture model incorporating orbital mechanical stimulation to better replicate intestinal conditions and investigate nanoparticle interactions.
Methods: We established co-cultures under static and dynamic conditions, evaluating their development through multiple approaches including barrier integrity measurements, gene expression analysis, and confocal microscopy.
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