Magnesium amide complexes such as Mg{N(SiMe)} (1) LMgN(SiMe)·THF (2) [L = ArNC(NPr)NAr; (Ar = 2,6-Me-CH)] and LMgN(SiMe)·THF (3) [L = ArNC(NPr)NAr; (Ar = 2,6-Pr-CH)] are reported as highly efficient pre-catalysts for the hydroboration of a wide range of esters using pinacolborane (HBpin) under mild reaction conditions. Moreover, we have shown compound 1 catalyzed chemoselective reduction of esters in the presence of other reducible functional groups such as alkene, alkyne and nitro.
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