AI Article Synopsis
- The study investigates the chemistry of giant fullerene C, focusing on the synthesis of chloro derivatives from three specific isomers (234, 812, 811).
- In C(234)Cl, two versions with different numbers of Cl atoms (16 and 18) share the same crystallographic position in a specific ratio.
- The findings highlight different chlorination patterns in C(812)Cl and C(811)Cl, demonstrating how small changes in chlorination significantly alter the structure.
Article Abstract
The chemistry of a giant fullerene, C , has been extended by the synthesis and structural study of several chloro derivatives of three isolated pentagon rule (IPR) isomers of C nos. 234, 812, and 811. In the structure of C (234)Cl , two molecules with 16 and 18 attached Cl atoms occupy the same crystallographic site with an occupancy ratio of 61/39. The structures of C (812)Cl and C (812)Cl demonstrate substructure relationships of their chlorination patterns with single and double Cl attachments to 12 cage pentagons. The structure of C (811)Cl is compared with the known C (811)Cl thus revealing dramatic changes in the chlorination pattern, which occur with relatively small increases in the degree of chlorination.
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| http://dx.doi.org/10.1002/chem.201700079 | DOI Listing |
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