Laser controlled charge-transfer reaction at low temperatures.

J Chem Phys

Department of Physics, Temple University, Philadelphia, Pennsylvania 19122, USA.

Published: February 2017

We study the low-temperature charge transfer reaction between a neutral atom and an ion under the influence of near-resonant laser light. By setting up a multi-channel model with field-dressed states, we demonstrate that the reaction rate coefficient can be enhanced by several orders of magnitude with laser intensities of 10 W/cm or larger. In addition, depending on laser frequency, one can induce a significant enhancement or suppression of the charge-exchange rate coefficient. For our intensities, multi-photon processes are not important.

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http://dx.doi.org/10.1063/1.4976972DOI Listing

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