Selective photodissociation of tailored molecular tags as a tool for quantum optics.

Beilstein J Nanotechnol

Department of Chemistry, University of Basel, St. Johannsring 19, CH-4056 Basel, Switzerland; Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, D-76344 Eggenstein-Leopoldshafen, Germany; Lehn Institute of Functional Materials (LIFM), Sun Yat-Sen University (SYSU), Xingang Rd. W., Guangzhou, China.

Published: February 2017

Recent progress in synthetic chemistry and molecular quantum optics has enabled demonstrations of the quantum mechanical wave-particle duality for complex particles, with masses exceeding 10 kDa. Future experiments with even larger objects will require new optical preparation and manipulation methods that shall profit from the possibility to cleave a well-defined molecular tag from a larger parent molecule. Here we present the design and synthesis of two model compounds as well as evidence for the photoinduced beam depletion in high vacuum in one case.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5301912PMC
http://dx.doi.org/10.3762/bjnano.8.35DOI Listing

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