The surface plasmon self-interference excited by a strongly focused, linearly polarized vortex beam at off-axis illumination in a paraxial regime is analytically studied. The off-axis excitation is investigated using a geometrical model. The combination of an angular spectrum representation and homogeneous transformation is applied to derive the integral expressions of the surface plasmon polariton fields for off-axis directions both parallel and perpendicular to polarization plane, and an off-axis convergence angle is used to compute the integral. The surface plasmon excitation is represented by the relative peak intensity of the longitudinal field, while its standing wave is characterized by the full width at half-maximum of the transmitted field intensity distribution profile. Both models consistently show that even in ideal Gaussian microscopic imaging systems, self-interference degradation exists. When the off-axis angle increases, the surface plasmon interference disappears and the fields detune out of surface plasmon resonance.
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http://dx.doi.org/10.1364/OE.25.003534 | DOI Listing |
Adv Sci (Weinh)
January 2025
Department of Chemistry, Center for BioAnalytical Chemistry, Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology, Tsinghua University, Beijing, 100084, China.
Single nanoparticle analysis is crucial for various applications in biology, materials, and energy. However, precisely profiling and monitoring weakly scattering nanoparticles remains challenging. Here, it is demonstrated that deep learning-empowered plasmonic microscopy (Deep-SM) enables precise sizing and collision detection of functional chemical and biological nanoparticles.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
The Organic Photonics and Electronics Group, Department of Physics, Umeå University, SE-90187 Umeå, Sweden.
Light-emitting electrochemical cells (LECs) are promising candidates for fully solution-processed lighting applications because they can comprise a single active-material layer and air-stable electrodes. While their performance is often claimed to be independent of the electrode material selection due to the in situ formation of electric double layers (EDLs), we demonstrate conceptually and experimentally that this understanding needs to be modified. Specifically, the exciton generation zone is observed to be affected by the electrode work function.
View Article and Find Full Text PDFNanomaterials (Basel)
December 2024
Department of Physics, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece.
Nanomaterials and nanostructures with different morphologies or geometrical shapes that exploit plasmons, and particularly surface plasmon polaritons, are useful for a wide range device fabrication-related applications [...
View Article and Find Full Text PDFNanoscale
January 2025
CNR - Istituto Nanoscienze, Modena, Italy.
Copper nanoparticles (NPs) can be coupled with cuprous oxide, combining photoelectrocatalytic properties with a broad-range optical absorption. In the present study, we aimed to correlate changes in morphology, electronic structure and plasmonic properties of Cu NPs at different stages of oxidation. We demonstrated the ability to monitor the oxidation of NPs at the nanometric level using STEM-EELS spectral maps, which were analyzed with machine learning algorithms.
View Article and Find Full Text PDFACS Nano
January 2025
Instituto de Física de São Carlos, Universidade de São Paulo, São Carlos 13566-590, Brazil.
Monolayers of transition-metal dichalcogenides, such as MoS, have attracted significant attention for their exceptional electronic and optical properties, positioning them as ideal candidates for advanced optoelectronic applications. Despite their strong excitonic effects, the atomic-scale thickness of these materials limits their light absorption efficiency, necessitating innovative strategies to enhance light-matter interactions. Plasmonic nanostructures offer a promising solution to overcome those challenges by amplifying the electromagnetic field and also introducing other mechanisms, such as hot electron injection.
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