A dihydroxy-substituted benzothienobenzothiophene, BTBT(OH), was synthesized, and its charge-transfer (CT) salt, β-[BTBT(OH)]ClO, was successfully obtained. Thanks to the introduced hydroxy groups, a hydrogen-bonded chain structure connecting the BTBT molecules and counter anions was formed in the CT salt, which effectively increases the dimensionality of the electronic structure and consequently leads to a stable metallic state.
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http://dx.doi.org/10.1039/c7cc00784a | DOI Listing |
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