A novel cleaner ethanol production process has been developed. Thin stillage is treated initially by anaerobic digestion followed by aerobic digestion and then further treated by chloride anion exchange resin. This allows the fully-digested and resin-treated stillage to be completely recycled for use as process water in the next ethanol fermentation batch, which eliminates wastewater discharges and minimizes consumption of fresh water. The method was evaluated at the laboratory scale. Process parameters were very similar to those found using tap water. Maximal ethanol production rate in the fully-recycled stillage was 0.9g/L/h, which was similar to the 0.9g/L/h found with the tap water control. The consumption of fresh water was reduced from 4.1L/L (fresh water/ethanol) to zero. Compared with anaerobically-aerobically digested stillage which had not been treated with resin, the fermentation time was reduced by 28% (from 72h to 52h) and reached the level achieved with tap water. This novel process can assist in sustainable development of the ethanol industry.
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http://dx.doi.org/10.1016/j.wasman.2017.01.040 | DOI Listing |
Sci Total Environ
January 2025
Departamento de Geodinámica, Estratigrafía y Paleontología, Facultad de Ciencias Geológicas, Universidad Complutense de Madrid, Calle José Antonio Nováis 12, 28040 Madrid, Spain.
In 2021 Spain passed a new law regarding the quality of drinking water, increasing the transparency and introducing a risk assessment approach to the catchment area, which ascribe to the shift in recent years in how drinking water management is understood in the European Union legislation. Good data quality is important to ensure the correct implementation of policies. We used the drinking quality data uploaded to Spain's National Drinking Water Information System to gauge the state of the drinking water reporting in Spain, the differences between rural urban and rural areas in both quality and reporting and identify which variables at catchment level influence the probability of a municipality incurring in drinking water quality non-compliance.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
Ministry of Education Key Laboratory of Analytical Science for Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fujian, Fuzhou 350108, China. Electronic address:
Phenolic compounds are a kind of persistent organic pollutants (POPs), which are always a threat to human and environment due to their strong toxicity and low biodegradability. Therefore, developing a reliable method to simultaneously detect phenolic pollutants is of great importance to environmental safety and human health. Herein, we combined the advantages of metal organic frameworks (MOFs) and covalent organic frameworks (COFs) to prepare two cyclic trinuclear unit-based metal covalent organic framework (MCOFs, denoted as Cu-TDH COF and Cu-BDU COF) with large specific surface area, good stability and excellent laccase-like activity.
View Article and Find Full Text PDFHeliyon
January 2025
Department of Chemical Engineering, School of Chemical and Materials Engineering (SCME), National University of Sciences & Technology (NUST), Sector H-12, Islamabad, 44000, Pakistan.
This study examines the viability of using graphitic-Carbon Nitride (g-CN) nanomaterial as shale stabilizer drilling fluid additive having applications in the oil and gas wells drilling. Shale stability is important especially when drilling horizontal and extended reach wells with water-based muds (WBM) to tap unconventional reservoirs namely shale oil and shale gas. For this study, the g-CN nanomaterial was produced by melamine pyrolysis, and characterized by X-Ray Diffraction, Scanning Electron Microscopy and Fourier Transform Infrared spectroscopy techniques.
View Article and Find Full Text PDFJ Dent Sci
December 2024
Division of Molecular and Regenerative Prosthodontics, Tohoku University Graduate School of Dentistry, Sendai, Japan.
Background/purpose: Daily flushing of dental unit waterlines is important for infection control. However, the effect of flushing on water quality management in portable dental units (PDUs) for mobile dental treatments remains unclear. In this study, we aimed to investigate the factors affecting the effectiveness of PDU flushing.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
School of Chemistry, The University of Sydney, Sydney, NSW 2006, Australia.
Designing molecular receptors that bind anions in water is a significant challenge, and an even greater difficulty lies in using these receptors to remove anions from water without resorting to the hazardous liquid-liquid extraction approach. We here demonstrate an effective and synthetically simple strategy toward these goals by exploiting ion-pair assembly of macrocycles. Our anion binding ensemble consists of an octa-chloro tetra-urea macrocyclic anion receptor (ClTU), which forms water-dispersible aggregates, and a tetra-cationic fluorescent dye 5,10,15,20-tetrakis(1-methyl-4-pyridinio)porphyrin (TMPyP4), which provides Coulombic stabilization and fluorescence reporting of anion binding in an ion-pair assembly.
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