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Crystal structure of μ-chlorido-nona-kis-(μ-4-chloro-pyrazolato)bis-μ-methoxo-hexa-copper(II). | LitMetric
The hexa-nuclear title compound, [{Cu(μ-OCH)(μ-CHClN)}(μ-CHClN)(μ-Cl)] or [Cu(CHClN)(CHO)Cl], crystallizes in the space group , with individual mol-ecules being located on a twofold rotation axis. The mol-ecule adopts a trigonal prismatic shape, with two trinuclear units linked by three 4-chloro-pyrazolate ligand bridges by encapsulating a Cl anion in a μ-coordination mode. In the crystal, individual mol-ecules are stacked into rods parallel to [1-10] that are arranged in a pseudo-hexa-gonal packing. Cohesion between mol-ecules is accomplished through weak C-H⋯Cl inter-actions.
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structure μ-chlorido-nona-kis-μ-4-chloro-pyrazolatobis-μ-methoxo-hexa-copperii
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μ-chlorido-nona-kis-μ-4-chloro-pyrazolatobis-μ-methoxo-hexa-copperii hexa-nuclear
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compound [{cuμ-ochμ-chcln}μ-chclnμ-cl]
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[{cuμ-ochμ-chcln}μ-chclnμ-cl] [cuchclnchocl]
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[cuchclnchocl] crystallizes
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