In the title compound, [Cu(CHCOO)(CHNO)] , the Cu ion resides on a centre of inversion, displaying a tetra-gonally distorted octa-hedral coordination environment defined by two pairs of N and O atoms of symmetry-related 4-(1-imidazol-1-yl)phenol ligands and the O atoms of two symmetry-related acetate ligands. The bridging mode of the 4-(1-imidazol-1-yl)phenol ligands is associated with a very long Cu⋯O inter-actions involving the phenol O atom of the heterocyclic ligand, which creates chains extending parallel to [100]. In the crystal, the chains are arranged in a distorted hexa-gonal rod packing and are linked C-H⋯O hydrogen bonds and by π-π stacking inter-actions involving centrosymmetrically related pairs of imidazole and phenol rings.
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| http://dx.doi.org/10.1107/S2056989017000780 | DOI Listing |
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