Crystal structure of ()--[(anthracen-9-yl)methyl-idene]--phenyl-benzene-1,4-di-amine.

Acta Crystallogr E Crystallogr Commun

National Taras Shevchenko University, Department of Chemistry, Volodymyrska str. 64, 01601 Kyiv, Ukraine.

Published: February 2017

The title compound, CHN, a Schiff base synthesized a condensation reaction between anthracene-9-carbaldehyde and -phenyl--phenyl-enedi-amine, crystallizes with three independent mol-ecules in the asymmetric unit. The three mol-ecules have slightly varying overall conformations, all having conformations with respect to the C=N bond. In the crystal, the packing features N-H⋯N hydrogen bonds, which connect mol-ecules into chains extending along the -axis direction, inter-linked by C-H⋯π inter-actions (minimum H⋯ = 2.65 Å) into sheets lying parallel to (001).

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290551PMC
http://dx.doi.org/10.1107/S2056989016020612DOI Listing

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