Crystal structure of 7,15-bis-(4--butyl-phen-yl)-1,9-di-methyl-hepta-zethrene.

Acta Crystallogr E Crystallogr Commun

Advanced Institute for Materials Research, Tohoku University, Aoba-ku, Sendai 980-8577, Japan; JST, ERATO, Isobe Degenerate π-Integration Project, Aoba-ku, Sendai 980-8577, Japan; Department of Chemistry, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.

Published: February 2017

The title compound, CH, , was synthesized as a derivative of hepta-zethrene bearing two methyl and two -butyl-phenyl substituents, respectively, at the 1,9- and 7,15-positions. The asymmetric unit consists of one half of the mol-ecule, which lies about an inversion centre. Albeit remotely located, the substituents contort the hepta-zethrene plane. The -butyl-phenyl substituents stand approximately perpendicular to the core plane, with a dihedral angle of 79.09 (5)° between the phenalene ring system and the substituted benzene ring, and prevent direct inter-molecular contacts of the hepta-zethrene cores.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290542PMC
http://dx.doi.org/10.1107/S2056989016020247DOI Listing

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