The title compound, CH, , was synthesized as a derivative of hepta-zethrene bearing two methyl and two -butyl-phenyl substituents, respectively, at the 1,9- and 7,15-positions. The asymmetric unit consists of one half of the mol-ecule, which lies about an inversion centre. Albeit remotely located, the substituents contort the hepta-zethrene plane. The -butyl-phenyl substituents stand approximately perpendicular to the core plane, with a dihedral angle of 79.09 (5)° between the phenalene ring system and the substituted benzene ring, and prevent direct inter-molecular contacts of the hepta-zethrene cores.
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http://dx.doi.org/10.1107/S2056989016020247 | DOI Listing |
Chemistry
November 2024
Department of Chemistry, University of New Hampshire, 23 Academic Way, Durham, New Hampshire, 03824, USA.
Acenes are notable for their optoelectronic properties and applications in organic electronics. Starphenes are structurally related molecules possessing three acene arms that radiate linearly from a central benzene ring (i. e.
View Article and Find Full Text PDFJ Am Chem Soc
July 2024
Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, Georgia 30322, United States.
Dirhodium tetrakis(2,2'-binaphthylphosphate) catalysts were successfully developed for asymmetric C-H functionalization with trichloroethyl aryldiazoacetates as the carbene precursors. The 2,2'-binaphthylphosphate (BNP) ligands were modified by introduction of aryl and/or chloro functionality at the 4,4',6,6' positions. As the BNP ligands are C-symmetric, the resulting dirhodium tetrakis(2,2'-binaphthylphosphate) complexes were expected to be D-symmetric, but X-ray crystallographic and computational studies revealed this is not always the case because of internal T-shaped CH-π and aryl-aryl interactions between the ligands.
View Article and Find Full Text PDFMolecules
May 2024
Department of Organic and Medicinal Chemistry, Faculty of Chemistry, Wroclaw University of Science and Technology, 27 Wybrzeże Wyspiańskiego, 50-370 Wroclaw, Poland.
The research on new compounds against plant pathogens is still socially and economically important. It results from the increasing resistance of pests to plant protection products and the need to maintain high yields of crops, particularly oilseed crops used to manufacture edible and industrial oils and biofuels. We tested thirty-five semi-synthetic hydrazide-hydrazones with aromatic fragments of natural origin against phytopathogenic laccase-producing fungi such as , , and .
View Article and Find Full Text PDFAngew Chem Int Ed Engl
April 2024
Shenzhen Key Laboratory of New Information Display and Storage Materials, College of Materials Science and Engineering, Shenzhen University, Shenzhen, 518060, P. R. China.
1,4-BN-doped polycyclic aromatic hydrocarbons (PAHs) have emerged as very promising emitters in organic light-emitting diodes (OLEDs) due to their narrowband emission spectra that may find application in high-definition displays. While considerable research has focused on investigating the properties of these materials, less attention has been placed on their synthetic methodology. Here we developed an efficient synthetic method for 1,4-BN-doped PAHs, which enables sustainable production of narrowband organic emitting materials.
View Article and Find Full Text PDFActa Crystallogr E Crystallogr Commun
March 2023
University Koblenz, Institute of Integrated Natural Sciences, Universitätsstr. 1, 56070 Koblenz, Germany.
The title compound, [Fe(CH)(CHNO)], which is produced by the oxidation of 1-(4--butyl-phen-yl)-2-ethyl-3-ferrocenyl-pyrrole, crystallizes as a racemic mixture in the centrosymmetric space group 2/. The central heterocyclic pyrrole ring system subtends dihedral angles of 13.7 (2)° with respect to the attached cyclo-penta-dienyl ring and of 43.
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