Indium-oxide (InO) nanobelts coated by a 5-nm-thick carbon layer provide an enhanced photocatalytic reduction of CO to CO and CH, yielding CO and CH evolution rates of 126.6 and 27.9 μmol h, respectively, with water as reductant and Pt as co-catalyst. The carbon coat promotes the absorption of visible light, improves the separation of photoinduced electron-hole pairs, increases the chemisorption of CO, makes more protons from water splitting participate in CO reduction, and thereby facilitates the photocatalytic reduction of CO to CO and CH.
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http://dx.doi.org/10.1021/jacs.7b00266 | DOI Listing |
Dent Mater
January 2025
Department of Oral Health Sciences, Faculty of Dentistry, The University of British Columbia, 2199 Wesbrook Mall, room 352, BC V6T-1Z3, Canada. Electronic address:
Objectives: This study aimed to assess the potential of experimental dental resins containing ZnO nanoparticles (ZnO-NPs) for antimicrobial photodynamic therapy (aPDT) as a functional tool for the modulation of cariogenic biofilm in long-term.
Methods: Minimum inhibitory and bactericidal concentrations (MIC/MBC) of ZnO-NPs against Streptococcus mutans were initially determined under different energy densities of blue LED irradiation (0.00, 1.
J Colloid Interface Sci
January 2025
College of Materials and Chemistry, China Jiliang University, 258 Xueyuan Street, Xiasha Higher Education Zone, Hangzhou 310018, China. Electronic address:
6PPD-quinone (6PPD-Q) as a derivative of the rubber antioxidant N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine (6PPD), is attracting intensive attention due to the significant hazard to ecosystems. However, the effective management of this type of contaminant has been scarcely reported. Hydrangea-like hollow O, Cl-codoped graphite-phase carbon nitride microspheres (HHCN), featuring open pores were readily prepared by molecular self-assembly and utilized to address 6PPD-Q in an aqueous system for the first time.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Plant Protection, Faculty of Agriculture, Urmia University, Urmia, Iran.
This study investigates the biosynthesis of iron oxide nanoparticles (FeONPs) using the cell-free supernatant of Pseudomonas fluorescens. The synthesized FeONPs were characterized through UV-VIS, XRD, FTIR, FESEM, EDX, TEM, BET, and VSM analyses. The XRD results confirmed that FeONPs were successfully synthesized and EDX analysis indicated that iron accounted for 89.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Key Laboratory of Organosilicon Chemistry and Materials Technology, Ministry of Education; College of Materials Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou, Zhejiang 311121, China. Electronic address:
Keto reductases are crucial NAD(P)H-dependent enzymes used for the enantioselective synthesis of alcohols from prochiral ketones. Typically, the NADPH cofactor is regenerated through a second enzyme and/or substrate. However, photocatalytic cofactor regeneration using water as a sacrificial electron and hydrogen donor presents a promising alternative, albeit a challenging one.
View Article and Find Full Text PDFEnviron Res
January 2025
Xi'an Key Laboratory of Advanced Photo-Electronics Materials and Energy Conversion Device, Technological Institute of Materials & Energy Science (TIMES), Xijing University, Xi'an 710123, PR China; School of Artificial Intelligence, Optics and Electronics (iOPEN), Northwestern Polytechnical University, Xi'an 710072, Shaanxi, PR China. Electronic address:
This paper focuses on the research background of zeolite-based photocatalytic materials, the role of zeolites in photocatalytic materials, and their application in various fields. It focuses on the critical roles of zeolites in photocatalytic materials and their application prospects. It outlines the mechanisms of zeolites in different photocatalytic materials, including adsorption, structural stabilization, domain-limiting, electric field, catalysis, ion exchange, shape-selective, and solvation, which elucidates the potential advantages of zeolites in photocatalytic materials.
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