Background: This study aimed to evaluate the effect of different percentages of ethanol solvent of an experimental methacrylate-based dentin bonding agent containing polyhedral oligomeric silsesquioxanes (POSS) on the microleakage of resin composite restorations.
Materials And Methods: In this experimental study, 42 extracted human premolar teeth used and 84 standard Class V cavities were prepared on the buccal and lingual surfaces of the teeth. The teeth were divided into 6 groups of 7. Experimental bonding agents with different percentages of solvent were used in 5 groups and Single Bond as a control. The teeth were restored with resin composite and subjected to thermal cycling test. Teeth were then immersed in a solution of 2% basic fuchsine dye for 24 h and sectioned buccolingually and scored using stereomicroscope with ×32 magnification. Microleakage data were analyzed using the Kruskal-Wallis, Mann-Whitney U, and Wilcoxon tests.
Results: There were significant differences between the microleakage enamel margins ( = 0.036) and dentinal margins ( = 0.008) in all the groups. These significant differences were seen between the control group and groups containing 46 wt% solvent ( = 0.011), 46 wt% and 31 wt% solvent in dentinal ( = 0.027), 31 wt% and 0 wt% in enamel ( = 0.021), also 0 wt% and control in enamel ( = 0.039), and dentinal margins microleakage ( = 0.004). The microleakage in dentinal margins was higher than enamel margins ( < 0.001). In the groups with 46 wt% solvent ( = 0.103), 0 wt% ( = 0.122), and control group ( = 0.096), however, this difference was not significant.
Conclusion: The adhesive containing 31 wt% solvent showed the least marginal microleakage, presence of POSS filler may also result in the reduction of microleakage.
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http://dx.doi.org/10.4103/1735-3327.197032 | DOI Listing |
Nat Commun
January 2025
Van 't Hoff Institute for Molecular Sciences, University of Amsterdam, Amsterdam, The Netherlands.
As a result of the current high throughput of the fast fashion collections and the concomitant decrease in product lifetime, we are facing enormous amounts of textile waste. Since textiles are often a blend of multiple fibers (predominantly cotton and polyester) and contain various different components, proper waste management and recycling are challenging. Here, we describe a high-yield process for the sequential chemical recycling of cotton and polyester from mixed waste textiles.
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Materials Science and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology, Trivandrum 695 019, Kerala, India.
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January 2025
Zhejiang Provincial Engineering Research Center for Green and Low-carbon Dyeing & Finishing, Zhejiang Sci-Tech University, Hangzhou 310018, China; Zhejiang Provincial Innovation Center of Advanced Textile Technology, Shaoxing 312000, China. Electronic address:
Comparing to the solvent-based and waterborne polyurethanes (PU), the solvent-free reactive PU (RPU) is prepared via in-situ polymerization and film-formation of isocyanate-capped prepolymers and macromolecular polyols in solvent-free system. Thus, the carbon emissions and environmental pollutions are significantly reduced. However, the rapid polymerization also challenges the well control of structure and properties, especially the ordered microstructures.
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January 2025
Qatar Environment and Energy Research Institute, Hamad Bin Khalifa University, Qatar Foundation, Doha P.O. Box 34110, Qatar.
The development of ultrafiltration (UF) polymeric membranes with high flux and enhanced antifouling properties bridges a critical gap in the polymeric membrane fabrication research field. In the present work, the preparation of novel PES membranes incorporated with carrageenan (CAR), which is a natural polymer derived from edible red seaweed, is reported for the first time. The PES/CAR membranes were prepared by using the nonsolvent-induced phase separation (NIPS) method at 0.
View Article and Find Full Text PDFPolymers (Basel)
January 2025
Dipartimento di Chimica "G. Ciamician", Alma Mater Studiorum-Università di Bologna, Via F. Selmi 2, 40126 Bologna, Italy.
The development of greener substitutes for plastics is gaining massive importance in today's society. This also involves the medical field, where disposable materials are used to grant sterility. Here, a novel protocol using only a water-based solvent for the preparation of bio-based composite foams of actual β-chitin and collagen type I is presented.
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