Diamond-like carbon (DLC) material is used in blood contacting devices as the surface coating material because of the antithrombogenicity behavior which helps to inhibit platelet adhesion and activation. In this study, DLC films were doped with boron during pulsed plasma chemical vapor deposition (CVD) to improve the blood compatibility. The ratio of boron to carbon (B/C) was varied from 0 to 0.4 in the film by adjusting the flow rate of trimethylboron and acetylene. Tribological tests indicated that boron doping with a low B/C ratio of 0.03 is beneficial for reducing friction (μ = 0.1), lowering hardness and slightly increasing wear rate compared to undoped DLC films. The B/C ratio in the film of 0.03 and 0.4 exhibited highly hydrophilic surface owing to their high wettability and high surface energy. An platelet adhesion experiment was conducted to compare the blood compatibility of TiNb substrates before and after coating with undoped and boron doped DLC. Films with highly hydrophilic surface enhanced the blood compatibility of TiNb, and the best results were obtained for DLC with the B/C ratio of 0.03. Boron doped DLC films are promising surface coatings for blood contacting devices.
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http://dx.doi.org/10.1080/14686996.2016.1262196 | DOI Listing |
Heliyon
November 2024
Faculty of Physics, Shahrood University of Technology, 3619995161, Shahrood, Iran.
This study evaluates the deposition of diamond-like carbon (DLC) films with copper impurities on a glass substrate using simultaneous direct current (DC) and radio frequency (RF) magnetron sputtering. The structural, optical, electrical, and mechanical properties, as well as the surface topography of the films, were investigated under various DC power levels using Raman spectroscopy, ellipsometry, UV-VIS, I-V measurements, nanoindentation, AFM, and FESEM. Results indicate that increasing the DC power to the graphite target from 60 to 120 , while maintaining a constant 10 of RF power to the copper target, enhances the optical absorption coefficient of the films and increases the optical bandgap from 0.
View Article and Find Full Text PDFMaterials (Basel)
November 2024
Department of Applied Pharmacy, Faculty of Pharmacy, Medical University of Lodz, Jana Muszyńskiego 1, 90-001 Lodz, Poland.
The potential of diamond-like carbon coatings in medicine can be increased by doping them with various elements. Such modifications especially affect the biological properties of the synthetized films. In the following research, phosphorus was introduced into the carbon matrix by means of the chemical vapor deposition technique and using an organic precursor.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
November 2024
Center for Nano and Micro Mechanics, School of Aerospace Engineering, Tsinghua University, Beijing 100084, China.
ACS Appl Mater Interfaces
November 2024
Key Laboratory of Science and Technology on Wear and Protection of Materials, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, PR China.
Achieving fast and long-lasting superlubricity in two-dimensional (2D) materials under high-stress conditions is challenging due to their susceptibility to structural deformations, limited load-bearing capacity, oxidation, and thermal degradation. This study introduces an innovative strategy by utilizing a composite of MXene and H-DLC, where, under high-stress conditions, H-DLC acts as a preferential energy-absorbing phase. MXene serves as a template to rapidly and continuously transform the absorbed energy into graphene-like structures, forming an in situ heterogeneous MXene/graphene-like interface.
View Article and Find Full Text PDFHeliyon
October 2024
School of Intelligent Manufacturing Engineering, Harbin Huade University, Harbin, 150025, Heilongjiang, China.
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