Mitigation of methane emissions in a pilot-scale biocover system at the AV Miljø Landfill, Denmark: 2. Methane oxidation.

Greenhouse gas mitigation at landfills by methane (CH) oxidation in engineered biocover systems is believed to be a cost effective technology but so far a full quantitative evaluation of the efficiency of the technology in full scale has only been carried out in a few cases. A third generation semi-passive biocover system was constructed at the AV Miljø Landfill, Denmark. The biocover was fed by landfill gas pumped out of three leachate collection wells. An innovative gas distribution system was used to overcome the often observed uneven gas distribution to the active CH oxidation layer resulting in overloaded areas causing CH emission hot spot areas in the biocover surface. The whole biocover CH oxidation efficiency was determined by measuring the CH inlet load and CH surface fluxes. In addition, CH oxidation was determined for single points in the biocover using two different methods; the carbon mass balance method (based on CH and carbon dioxide (CO) concentrations in the deeper part of the cover and CH and CO surface flux measurements) and a new-developed tracer gas mass balance method (based on CH and tracer inlet fluxes and CH and tracer surface flux measurements). Overall, the CH oxidation efficiency of the whole biocover varied between 81 and 100% and showed that the pilot plant biocover system installed at AV Miljø landfill was very efficient in oxidizing the landfill CH. The average CH oxidation rate measured at nine campaigns was approximately 13gmd. Extrapolating laboratory measured CH oxidation rates to the field showed that the biocover system had a much larger CH oxidation potential in comparison to the tested CH load. The carbon mass balance approach compared reasonably well with the tracer gas mass balance approach when applied for quantification of CH oxidation in single points at the biofilter giving CH oxidation efficiencies in the range of 84 to a 100%. CH oxidation rates where however much higher using the tracer gas balance method giving CH oxidation rates between 7 and 124gmd compared to the carbon mass balance, which gave CH oxidation rates -0.06 and 40gmd. The study also revealed that the compost respiration contributed significantly to the measured CO surface emission, and that the contribution of the compost respiration decreased significantly with time probably due to further maturation of the compost material.