A novel, near-ultraviolet-excited white-light-emitting phosphor SrLa(PO):Eu, Mn was synthesized by the solid-state method. Luminescence properties and the energy transfer mechanism were investigated in detail by photoluminescence spectra and decay curves. With the energy transfer between Eu and Mn, a cold white light with chromaticity coordinates of (0.2790, 0.2273), correlated color temperature of 6501 K, Ra of 70, and external quantum efficiency of 35.5% was realized by changing the ratios of Eu and Mn in the SrLa(PO):Eu, Mn phosphors. Resonant energy transfer from Eu to Mn ions has been demonstrated to be a dipole-dipole mechanism in SrLa(PO). The energy transfer efficiency increases with Mn concentration increasing, and reaches a maximum of 55.6%.
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http://dx.doi.org/10.1364/AO.56.001167 | DOI Listing |
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