Dispersion cancellation with an energy-time entangled photon pair in Hong-Ou-Mandel (HOM) interference is one phenomenon that reveals the nonclassical nature of the entangled photon pair. This phenomenon has been observed in materials with very weak dispersions. If the higher-order dispersion coefficient is non-negligible, then the experiment must be modified to realize dispersion cancellation. All-order dispersion cancellation using balanced dispersion was suggested by Steinberg. However, the same phenomenon is expected to occur even if a photon pair is not entangled. This behaviour can be explained by path indistinguishability with identical dispersion. To achieve an all-order dispersion experiment that cannot be explained classically, we modified the experiment and performed another all-order dispersion cancellation experiment that cannot be explained by identical dispersion. This is the first demonstration of nonclassical all-order dispersion cancellation.
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http://dx.doi.org/10.1364/OE.25.001360 | DOI Listing |
Mol Biol Cell
December 2024
Graduate School of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo 153-8902, Japan.
The question of how changes in chemoattractant concentration translate into the chemotactic response of immune cells serves as a paradigm for the quantitative understanding of how cells perceive and process temporal and spatial information. Here, using a microfluidic approach, we analyzed the migration of neutrophil-like HL-60 cells to a traveling wave of the chemoattractants fMLP and leukotriene B4 (LTB4). We found that under a pulsatile wave that travels at a speed of 95 and 170 µm/min, cells move forward in the front of the wave but slow down and randomly orient at the back due to temporal decrease in the attractant concentration.
View Article and Find Full Text PDFJ Chem Phys
September 2024
Center for Computational Molecular Science and Technology, School of Chemistry and Biochemistry, and School of Computational Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332-0400, USA.
Symmetry-adapted perturbation theory (SAPT) directly computes intermolecular interaction energy in terms of electrostatics, exchange-repulsion, induction/polarization, and London dispersion components. In SAPT based on Hartree-Fock ("SAPT0") or based on density functional theory, the most time-consuming step is the computation of the dispersion terms. Previous work has explored the replacement of these expensive dispersion terms with simple damped asymptotic models.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
November 2024
EaStCHEM School of Chemistry, University of Edinburgh, Joseph Black Building, Edinburgh, EH9 3FJ, U.K.
Solvent competition for London dispersion attenuates its energetic significance in molecular recognition processes. By varying both the stacked contact area and the solvent, here we experimentally deconvolute solvent attenuation using molecular balances. Experimental stacking energies (phenyl to pyrene) correlated strongly with calculations only when dispersion was considered.
View Article and Find Full Text PDFElectronic textiles (E-textiles) offer great wearing comfort and unobtrusiveness, thus holding potential for next-generation health monitoring wearables. However, the practical implementation is hampered by challenges associated with poor signal quality, substantial motion artifacts, durability for long-term usage, and non-ideal user experience. Here, we report a cost-effective E-textile system that features 3D microfiber-based electrodes for greatly increasing the surface area.
View Article and Find Full Text PDFJ Chem Theory Comput
July 2024
Department of Physics and Engineering Physics, Tulane University, New Orleans, Louisiana 70118, United States.
Bolstered by recent calculations of exact functional-driven errors (FEs) and density-driven errors (DEs) of semilocal density functionals in the water dimer binding energy [Kanungo, B. 2024, 15, 323-328], we investigate approximate FEs and DEs in neutral water clusters containing up to 20 monomers, charged water clusters, and alkali- and halide-water clusters. Our proxy for the exact density is rSCAN 50, a 50% global hybrid of exact exchange with rSCAN, which may be less correct than rSCAN for the compact water monomer but importantly more correct for long-range electron transfers in the noncompact water clusters.
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