The authors create a zinc(ii) complex featuring a simple chemical structure but multi-functional luminochromism. Reversible dissociation/association between the zinc center and the terpyridine ligand plays a key role in the multi-functional luminochromism.
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Mechano-, thermo-, solvato-, and vapochromism in bis(acetato-κO)[4'-(4-(diphenylamino)phenyl)](2,2':6',2''-terpyridine-κN,N',N'')zinc(ii) and its polymer.
Chem Commun (Camb)
August 2017
Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
The titled complex exhibits multi-functional luminochromism in the solid state, despite its simple chemical structure. The complex shows solid-state vapochromism and mechanochromism. The polymer analogue of the complex undergoes solvatochromism and thermochromism.
View Article and Find Full Text PDFA simple zinc(ii) complex that features multi-functional luminochromism induced by reversible ligand dissociation.
Chem Commun (Camb)
March 2017
Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
The authors create a zinc(ii) complex featuring a simple chemical structure but multi-functional luminochromism. Reversible dissociation/association between the zinc center and the terpyridine ligand plays a key role in the multi-functional luminochromism.
View Article and Find Full Text PDFAchieving remarkable mechanochromism and white-light emission with thermally activated delayed fluorescence through the molecular heredity principle.
Chem Sci
March 2016
Department of Chemistry , Durham University, DH1 3LE , UK . Email:
Achieving high contrast mechanochromism (Δ > 100 nm) and white-light emission under mild conditions from a single compound with a simple structure is a great challenge. Herein, we report a novel dual-emissive compound, namely SCP, with an asymmetric molecular structure that fully inherits the photophysical properties of the parent molecules SC and SP. SCP shows high contrast, linearly tunable mechanochromism and bright white-light emission arising from a combination of traditional fluorescence and thermally activated delayed fluorescence (TADF).
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