Filled and empty states of Zn-TPP films deposited on Fe(001)-(1×1)O.

Beilstein J Nanotechnol

Department of Physics, Politecnico di Milano, p.za Leonardo da Vinci 32, 20133 Milano, Italy.

Published: October 2016

Zn-tetraphenylporphyrin (Zn-TPP) was deposited on a single layer of metal oxide, namely an Fe(001)-(1×1)O surface. The filled and empty electronic states were measured by means of UV photoemission and inverse photoemission spectroscopy on a single monolayer and a 20 monolayer thick film. The ionization energy and the electron affinity of the organic film were deduced and the interface dipole was determined and compared with data available in the literature.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238660PMC
http://dx.doi.org/10.3762/bjnano.7.146DOI Listing

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