Self-assembled nanocomposites have been extensively investigated due to the novel properties that can emerge when multiple material phases are combined. Growth of epitaxial nanocomposites using lattice-mismatched constituents also enables strain-engineering, which can be used to further enhance material properties. Here, we report self-assembled growth of highly tensile-strained Ge/InAlAs (InAlAs) nanocomposites by using spontaneous phase separation. Transmission electron microscopy shows a high density of single-crystalline germanium nanostructures coherently embedded in InAlAs without extended defects, and Raman spectroscopy reveals a 3.8% biaxial tensile strain in the germanium nanostructures. We also show that the strain in the germanium nanostructures can be tuned to 5.3% by altering the lattice constant of the matrix material, illustrating the versatility of epitaxial nanocomposites for strain engineering. Photoluminescence and electroluminescence results are then discussed to illustrate the potential for realizing devices based on this nanocomposite material.
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http://dx.doi.org/10.1038/ncomms14204 | DOI Listing |
Light Sci Appl
January 2025
Aalto University, Department of Electronics and Nanoengineering, Espoo, Finland.
Even though efficient near-infrared (NIR) detection is critical for numerous applications, state-of-the-art NIR detectors either suffer from limited capability of detecting incoming photons, i.e., have poor spectral responsivity, or are made of expensive group III-V non-CMOS compatible materials.
View Article and Find Full Text PDFSmall Methods
December 2024
School of Material Science and Engineering, National Institute of Technology Calicut, NIT Campus, Kozhikode, Kerala, 673601, India.
The work describes a novel sensing and transportation feasibility of the well-established antifungal drug Flucytosine (5-FC) using a 2D Silicon carbide (SiC) and Germanium-doped Silicon carbide (Ge@SiC) nanosheet via PBE level of Density functional theory. The computational study revealed that the drug molecules adhere to SiC and Ge@SiC sheets, maintaining their structural properties through physisorption on SiC and chemisorption on Ge@SiC. The charge transfer process associated with the adsorption is observed by Lowdin charge analysis and both the SiC and Ge@SiC sheets are identified as a feasible oxidation-based nanosensor for the drug.
View Article and Find Full Text PDFFood Chem
March 2025
College of Chemistry and Pharmacy, Northwest A&F University, Yangling, Shaanxi 712100, China. Electronic address:
β-lactoglobulin (β-lg) is the major allergen in dairy products, and poses a significant threat to special people including infants and young children. Therefore, a convenient, cost-efficient, and aptamer-free colorimetric sensing platform is developed for β-lg assay based on a germanium/zinc bimetallic oxide nanozyme (GeO/ZnO). The CTAB-assisted intercalation growth of ZnO nanoparticles between GeO layers endows GeO/ZnO with enhanced peroxidase-mimicking activity and β-lg affinity.
View Article and Find Full Text PDFSmall Methods
December 2024
Łukasiewicz Research Network - Institute of Microelectronics and Photonics, Aleja Lotników 32/46, 02-668, Warsaw, Poland.
A new class of optical fibers with cores composed of various glass nanorods requires a method to determine the internal structure. In particular, the identification of various ion distributions at the fiber cross-section with nanometer accuracy is required. For this purpose, the classical depth profiling mode of the secondary ion mass spectrometry technique is applied.
View Article and Find Full Text PDFACS Appl Mater Interfaces
November 2024
University of Michigan-Shanghai Jiao Tong University Joint Institute, Shanghai Jiao Tong University, Shanghai 200240, China.
Theranostics, by integrating diagnosis and therapy on a single platform, enables real-time monitoring of tumors during treatment. To improve the accuracy of tumor diagnosis, the fluorescence and photoacoustic imaging modalities can complement each other to achieve high resolution and a deep penetration depth. Despite the superior performance, the biodegradability of theranostic agents plays a critical role in enhancing nanoparticle excretion and reducing chronic toxicity, which is essential for clinical applications.
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