AI Article Synopsis
Article Abstract
The reaction of the methylidyne complex [W([triple bond, length as m-dash]CH)Br(CO)(dcpe)] (dcpe = 1,2-bis(dicyclohexylphosphino)ethane) with BuLi affords the intermediate anionic neopentylidyne complex Li[W([triple bond, length as m-dash]CBu)(CO)(dcpe)] which acts as a metal-based nucleophile towards BuCl, BuBr, PhE (E = S, Se, Te) and ClSnMe to afford the new carbyne complexes [W([triple bond, length as m-dash]CBu)(X)(CO)(dcpe)] (X = Cl, Br, EPh, SnMe).
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c6cc09718a | DOI Listing |
Publication Analysis
Top Keywords
bond length
12
[w[triple bond
8
anionic nucleophilic
4
nucleophilic carbyne
4
carbyne complex
4
complex reaction
4
reaction methylidyne
4
methylidyne complex
4
complex [w[triple
4
length m-dash]chbrcodcpe]
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!