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Design, synthesis and evaluation of new fluorinated liquid crystals bearing a CFCF fragment with negative dielectric anisotropy. | LitMetric

AI Article Synopsis

  • - The researchers created new negative dielectric molecules that feature a specific tricyclic structure, marking a significant advancement in synthetic methods using commercially available materials.
  • - They assessed the physical properties of these new mesogenic compounds, focusing on key traits like birefringence, dielectric anisotropy, and shear viscosity, which are crucial for liquid crystal (LC) display technologies.
  • - The findings revealed that these molecules possess strong negative dielectric anisotropy and birefringence, along with high viscosity, making them promising candidates for use in flat LC displays.

Article Abstract

We designed unique negative dielectric molecules, which were tricyclic compounds with a 5,5,6,6-tetrafluorocyclohexa-1,3-diene moiety in the mesogen, and then for the first time developed an effective synthetic protocol from commercially available 4-bromo-3,3,4,4-tetrafluorobut-1-ene. We also evaluated their physical properties for new mesogenic compounds, such as birefringence, dielectric anisotropy and shear viscosity, which are important characteristics for flat LC display device applications. The molecules clearly showed not only a large negative dielectric anisotropy and birefringence but also high viscosity.

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Source
http://dx.doi.org/10.1039/c6ob02431aDOI Listing

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