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Cationic Au versus Au : Catalyst-Controlled Divergent Reactivity of Alkyne-Tethered Lactams. | LitMetric
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Cationic Au versus Au : Catalyst-Controlled Divergent Reactivity of Alkyne-Tethered Lactams.

Benito Alcaide Pedro Almendros Sara Cembellín Israel Fernández Teresa Martínez Del Campo

Chemistry

Grupo de LactamasyHeterociclos Bioactivos, Unidad Asociada al CSIC, Departamento de Química Orgánica I, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, 28040, Madrid, Spain.

Published: March 2017

Switchable reactivity through cationic gold-based catalyst control built on the oxidation state, namely cationic Au versus Au , has been achieved in the direct functionalization of 2-azetidinone-tethered alkynyl indoles.

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 Source
http://dx.doi.org/10.1002/chem.201700234DOI Listing

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