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Diethynyldiphenylsilane (1) and divinyldiphenylsilane (2) were functionalized by hydrosilylation reactions with HSiMeCl, HSiMeCl and HSiCl. Fluorination of the resulting compounds generates bidentate open-chain Lewis acids of increasing acidity. All semi-flexible [PhSi(CH[double bond, length as m-dash]CHSiFMe) (n = 1, 2, 3)] and flexible [PhSi(CH-CHSiFMe) (n = 1, 2, 3)] bidentate Lewis acids were obtained in good to excellent yields. The different fluoride ion complexation behavior was explored in detail by multinuclear (low temperature) NMR spectroscopy. The Lewis acidic bidentate molecules as well as the resulting mono- and bissilicates were completely characterized by NMR spectroscopy, mass spectrometry and in part by elemental analysis and X-ray diffraction experiments.
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