Fokker-Planck quantum master equation for mixed quantum-semiclassical dynamics.

J Chem Phys

Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemical Physics and iChEM and Synergetic Innovation Center of Quantum Information and Quantum Physics, University of Science and Technology of China, Hefei, Anhui 230026, China.

Published: January 2017

We revisit Caldeira-Leggett's quantum master equation representing mixed quantum-classical theory, but with limited applications. Proposed is a Fokker-Planck quantum master equation theory, with a generic bi-exponential correlation function description on semiclassical Brownian oscillators' environments. The new theory has caustic terms that bridge between the quantum description on primary systems and the semiclassical or quasi-classical description on environments. Various parametrization schemes, both analytical and numerical, for the generic bi-exponential environment bath correlation functions are proposed and scrutinized. The Fokker-Planck quantum master equation theory is of the same numerical cost as the original Caldeira-Leggett's approach but acquires a significantly broadened validity and accuracy range, as illustrated against the exact dynamics on model systems in quantum Brownian oscillators' environments, at moderately low temperatures.

Download full-text PDF

Source
http://dx.doi.org/10.1063/1.4973610DOI Listing

Publication Analysis

Top Keywords

quantum master
16
master equation
16
fokker-planck quantum
12
equation theory
8
generic bi-exponential
8
brownian oscillators'
8
oscillators' environments
8
quantum
5
master
4
equation
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!