Pincer-type complexes [OsH (CO){PyCH NHCH CH NHPtBu }] and [OsH (CO){HN(CH CH PiPr ) }] catalyze the disproportionation reaction of aldehydes via an outer-sphere bifunctional mechanism achieving turnover frequencies up to 14 000 h . The N-H group of the catalysts is a key player in this process, elucidated with the help of DFT calculations.
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Department of Chemistry and Biochemistry, Wilfrid Laurier University, 75 University Ave. W., Waterloo, ON, N2L 3C5, Canada.
Pincer-type complexes [OsH (CO){PyCH NHCH CH NHPtBu }] and [OsH (CO){HN(CH CH PiPr ) }] catalyze the disproportionation reaction of aldehydes via an outer-sphere bifunctional mechanism achieving turnover frequencies up to 14 000 h . The N-H group of the catalysts is a key player in this process, elucidated with the help of DFT calculations.
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