Cumulative effects of bamboo sawdust addition on pyrolysis of sewage sludge: Biochar properties and environmental risk from metals.

Bioresour Technol

Key Laboratory of Soil Contamination Bioremediation of Zhejiang Province, School of Environmental and Resource Sciences, Zhejiang Agriculture and Forestry University, 88 Huancheng North Road, Lin'an, Hangzhou 311300, China; Institute of Soil Science, Chinese Academy of Sciences, 71 East Beijing Road, Nanjing 210008, China.

Published: March 2017

AI Article Synopsis

  • A new biochar was created by mixing bamboo sawdust and sewage sludge in a 1:1 ratio through co-pyrolysis at temperatures of 400-600°C.
  • This process resulted in lower biochar yield but higher carbon content compared to using sewage sludge alone.
  • Additionally, co-pyrolysis helped convert toxic metals in sewage sludge into more stable forms, reducing their toxicity and environmental risks when the biochar is applied to land.

Article Abstract

A novel type of biochar was produced by mixing bamboo sawdust with sewage sludge (1:1, w/w) via a co-pyrolysis process at 400-600°C. Changes in physico-chemical properties and the intrinsic speciation of metals were investigated before and after pyrolysis. Co-pyrolysis resulted in a lower biochar yield but a higher C content in the end product compared with use of sludge alone as the raw material. FT-IR analysis indicates that phosphine derivatives containing PH bonds were formed in the co-pyrolyzed biochars. In addition, co-pyrolysis of sludge with bamboo sawdust transformed the potentially toxic metals in the sludge into more stable fractions, leading to a considerable decrease in their direct toxicity and bioavailability in the co-pyrolyzed biochar. In conclusion, the co-pyrolysis technology provides a feasible method for the safe disposal of metal-contaminated sewage sludge in an attempt to minimize the environmental risk from potentially toxic metals after land application.

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Source
http://dx.doi.org/10.1016/j.biortech.2016.12.103DOI Listing

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