The efficiency improvement of luminescent solar concentrators (LSCs) necessary for practical realization is currently hindered by one major loss mechanism: reabsorption of emitted photons by the luminophores. Recently, we explored a promising technique for reducing reabsorption and also improving directional emission in LSCs utilizing stimulated emission, rather than only spontaneous emission, with an inexpensive seed laser. In this work, a model is developed to quantify the gain (i.e. the amount of amplification of a low power seed laser propagating through the solar-pumped concentrator) of stimulated-LSCs (s-LSCs) considering the effects of different important physical parameters. The net optical output power, available for a small PV cell, from the concentrator can also be determined from the model, which indicates the performance of s-LSCs. Finally, the performance of different existing material systems is investigated using literature values of the parameters required for the model, and a set of optimal parameters is suggested for practical realization of such a device.
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http://dx.doi.org/10.1364/OE.24.0A1546 | DOI Listing |
Membranes (Basel)
January 2025
Department of Chemistry, RCSI, University of Medicine and Health Sciences, 123 St Stephen's Green, D02 YN77 Dublin, Ireland.
The endoplasmic reticulum and the internal nuclear compartments are intrinsically connected through the nuclear membrane, pores and lamina. High resolution imaging of each of these cellular features concurrently remains a significant challenge. To that end we have developed a new molecular nuclear membrane-endoplasmic reticulum (NM-ER) staining fluorophore with emission maxima at 650 nm.
View Article and Find Full Text PDFNano Lett
January 2025
Department of Materials Engineering Science, Osaka University, 1-3 Machikaneyama-cho, Toyonaka, Osaka 560-8531, Japan.
Optical manipulation of nanomaterials using light resonant with material excitations holds promise for enhancing optical forces and sorting particles by unique quantum properties. Conventional resonant optical sorting mainly relies on absorption and scattering forces, making it difficult to sort nanomaterials by specific emission lines. Furthermore, emission typically induces negligible force unless the material is highly anisotropic, limiting selective manipulation via emission characteristics.
View Article and Find Full Text PDFAnal Chem
January 2025
School of Biomedical Engineering, Shenzhen Key Laboratory for Nano-Biosensing Technology, Guangdong Key Laboratory of Biomedical Measurements and Ultrasound Imaging, Marshall Laboratory of Biomedical Engineering, Shenzhen University Medical School, Shenzhen University, Shenzhen 518060, China.
Aggregation-induced emission (AIE) or aggregation-induced emission enhancement (AIEE) has endowed gold species with responsive fluorescent properties, favoring their potential applications in sensing, imaging, and therapy. However, it remains an interesting challenge to fabricate fluorophores with both AIE and AIEE effects. Herein, we presented highly luminescent Au(I) thiolate nanocomplex-based biosensors with Zn induced-AIE and zeolite imidazolate framework (ZIF-8) induced-AIEE effects.
View Article and Find Full Text PDFElife
January 2025
Max Planck Institute for Metabolism Research, Department of Neuronal Control of Metabolism, Cologne, Germany.
Orexin signaling in the ventral tegmental area and substantia nigra promotes locomotion and reward processing, but it is not clear whether dopaminergic neurons directly mediate these effects. We show that dopaminergic neurons in these areas mainly express orexin receptor subtype 1 (Ox1R). In contrast, only a minor population in the medial ventral tegmental area express orexin receptor subtype 2 (Ox2R).
View Article and Find Full Text PDFJ Phys Chem Lett
January 2025
SCNU Environmental Research Institute, Guangdong Provincial Key Laboratory of Chemical Pollution and Environmental Safety & MOE Key Laboratory of Environmental Theoretical Chemistry, School of Environment, South China Normal University, Guangzhou 510006, China.
Two-dimensional (2D) electronic spectra of the phenylene ethynylene dendrimer with 2-ring and 3-ring branches were evaluated by combining the on-the-fly trajectory surface hopping nonadiabatic dynamics and the doorway-window simulation protocol. The ground state bleach (GSB), stimulated emission (SE), and excited-state absorption (ESA) contributions to the 2D signal were obtained and carefully analyzed. The results demonstrate that the ultrafast intramolecular nonadiabatic excited-state energy transfer (EET) from the 2-ring to the 3-ring units is comprehensively characterized by the SE and ESA signals.
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