Martensitic transformations which play an important role in metallurgical processes are analysed using group-subgroup relations and sphere-packing considerations. This approach is applied to the transformations between body-centred cubic (b.c.c.) and face-centred cubic (f.c.c.) phases and yields the orientation relations according to the Nishiyama-Wassermann, the Kurdjumov-Sachs and the Pitsch mechanisms. The models proposed by Pitsch and Schrader and by Burgers for the transition between b.c.c. and hexagonally closest-packed (h.c.p.) type structures can be interpreted analogously. In addition, two mechanisms for the transition between cubic f.c.c. and h.c.p. structures are described.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1107/S2053273316013425 | DOI Listing |
ACS Nano
January 2025
Department of Physics, National University of Singapore, Singapore 117551, Singapore.
Phase separation plays a crucial role in many natural and industrial processes, such as the formation of clouds and minerals and the distillation of crude oil. In metals and alloys, phase separation is an important approach often utilized to improve their mechanical strength for use in construction, automobile, and aerospace manufacturing. Despite its importance in many processes, the atomic details of phase separation are largely unknown.
View Article and Find Full Text PDFACS Nano
January 2025
School of Chemistry and Chemical Engineering, Key Laboratory of Hubei Province for Coal Conversion and New Carbon Materials, Wuhan University of Science and Technology, Wuhan 430081, P. R. China.
Due to the simultaneous activation of hydrogen peroxide (HO) and oxygen, Ru nanocrystals exhibit inherent peroxidase- and oxidase-like activities, thereby limiting their extensive application in biosensing. Phase engineering of Ru nanocrystals holds great promise for enhancing catalytic activity and selectivity but remains a challenge. Here, highly active Ru nanocrystals with a metastable face-centered cubic (fcc) structure were successfully synthesized via a facile wet-chemical method followed by an etching step, enabling selective activation of HO and demonstrating promising peroxidase-like activity.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Institute of Advanced Structure Technology, Beijing Institute of Technology, Beijing 100081, China.
Bionic bioceramic scaffolds are essential for achieving excellent implant properties and biocompatible behavior. In this study, inspired by the microstructure of natural bone, bionic hydroxyapatite (HAp) ceramic scaffolds with different structures (body-centered cubic (BCC), face-centered cubic (FCC), and gyroid Triply Periodic Minimal Surfaces (TPMSs)) and porosities (80 vol.%, 60 vol.
View Article and Find Full Text PDFEntropy (Basel)
November 2024
Institute of Materials, School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China.
Corrosion of soft magnetic materials during service can significantly impact their performance and service life, therefore it is important to improve their corrosion resistance. In this paper, the corrosion resistance, alternating current soft magnetic properties (AC SMPs) and microstructure of FeCoNiAl ( = 1.0-2.
View Article and Find Full Text PDFNat Commun
January 2025
College of Energy, Xiamen University, Xiamen, China.
The lack of high-efficiency platinum (Pt)-based nanomaterials remains a formidable and exigent challenge in achieving high formic acid oxidation reaction (FAOR) and membrane electrode assembly (MEA) catalysis for direct formic acid fuel cell (DFAFC) technology. Herein, we report 16 Pt-based heterophase nanotrepang with rare earth (RE)-doped face-centered cubic Pt (fcc-Pt) and trigonal Pt-tellurium (t-PtTe) configurations ((RE-Pt)-PtTe HPNT). Yttrium (Y) is identified as the optimal dopant, existing as single sites and clusters on the surface.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!