Nematic films at chemically structured surfaces.

J Phys Condens Matter

Centro de Física Teórica e Computacional, Departamento de Física, Faculdade de Ciências, Universidade de Lisboa, Campo Grande P-1749-016 Lisboa, Portugal.

Published: February 2017

We investigate theoretically the morphology of a thin nematic film adsorbed at flat substrate patterned by stripes with alternating aligning properties, normal and tangential respectively. We construct a simple 'exactly-solvable' effective interfacial model where the liquid crystal distortions are accounted for via an effective interface potential. We find that chemically patterned substrates can strongly deform the nematic-air interface. The amplitude of this substrate-induced undulations increases with decreasing average film thickness and with increasing surface pattern pitch. We find a regime where the interfacial deformation may be described in terms of a material-independent universal scaling function. Surprisingly, the predictions of the effective interfacial model agree semi-quantitatively with the results of the numerical solution of a full model based on the Landau-de Gennes theory coupled to a square-gradient phase field free energy functional for a two phase system.

Download full-text PDF

Source
http://dx.doi.org/10.1088/1361-648X/aa4fd6DOI Listing

Publication Analysis

Top Keywords

effective interfacial
8
interfacial model
8
nematic films
4
films chemically
4
chemically structured
4
structured surfaces
4
surfaces investigate
4
investigate theoretically
4
theoretically morphology
4
morphology thin
4

Similar Publications

Optimizing Nanobubble Production in Ceramic Membranes: Effects of Pore Size, Surface Hydrophobicity, and Flow Conditions on Bubble Characteristics and Oxygenation.

Langmuir

January 2025

John A. Reif, Jr. Department of Civil and Environmental Engineering, New Jersey Institute of Technology, 323 Martin Luther King Blvd., Newark, New Jersey 07102, United States.

Precise control of nanobubble size is essential for optimizing the efficiency and performance of nanobubble applications across diverse fields, such as agriculture, water treatment, and medicine. Producing fine bubbles, including nanobubbles, is commonly achieved by purging gas through porous media, such as ceramic or polymer membranes. Many operational factors and membrane properties can significantly influence nanobubble production and characteristics.

View Article and Find Full Text PDF

Underwater Superoleophobic and Transparent Films with Mechanical Robustness and High Durability in Harsh Environments.

ACS Appl Mater Interfaces

January 2025

Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China.

Underwater superoleophobic and transparent (UST) films are promising in applications, such as advanced optical devices in marine environments. However, the mechanical robustness and durability in harsh environments of the existing UST films are still unsatisfactory. In this work, we present a free-standing nacre-inspired mineralized UST (NIM-UST) film with high aragonite content and excellent mechanical properties toward robust underwater superoleophobicity on two surfaces and transparency (94%) in harsh seawater environments.

View Article and Find Full Text PDF

Lead halide perovskite heterojunctions have been considered as important building blocks for fabricating high-performance photodetectors (PDs). However, the interfacial defects induced non-radiative recombination and interfacial energy-level misalignment induced ineffective carrier transport severely limit the performance of photodetection of resulting devices. Herein, interfacial engineering with a spin-coating procedure has been studied to improve the photodetection performance of CHNHPbI/SnO heterojunction PDs, which were fabricated by sputtering a SnO thin film on ITO glass followed by spin-coating a CHNHPbI thin film.

View Article and Find Full Text PDF

Elucidating Thermal Decomposition Kinetic Mechanism of Charged Layered Oxide Cathode for Sodium-Ion Batteries.

Adv Mater

January 2025

Beijing Key Laboratory of Environmental Science and Engineering, School of Materials Science and Engineering, Beijing Institute of Technology, Beijing, 100081, China.

The safety of the P2-type layered transition metal oxides (P2-NaTMO), a promising cathode material for sodium-ion batteries (SIBs), is a prerequisite for grid-scale energy storage systems. However, previous thermal runaway studies mainly focused on morphological changes resulting from gas production detection and thermogravimetric analysis, while the structural transition and chemical reactions underlying these processes are still unclear. Herein, a comprehensive methodology to unveil an interplay mechanism among phase structures, interfacial microcrack, and thermal stability of the charged P2-NaNiMnO (NNMO) and the P2-NaNiLiMnO (NNMO-Li) at elevated temperatures is established.

View Article and Find Full Text PDF

Anode-free aqueous zinc metal batteries (AZMBs) offer significant potential for energy storage due to their low cost and environmental benefits. TiCT MXene provides several advantages over traditional metallic current collectors like Cu and Ti, including better Zn plating affinity, lightweight, and flexibility. However, self-freestanding MXene current collectors in AZMBs remain underexplored, likely due to challenges with Zn deposition reversibility.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!