H production in membraneless bioelectrochemical cells with optimized architecture: The effect of cathode surface area and electrode distance.

Chemosphere

Laboratory for Research on Advanced Processes for Water Treatment, Instituto de Ingeniería, Unidad Académica Juriquilla, Universidad Nacional Autónoma de México, Blvd. Juriquilla 3001, Querétaro, 76230, Mexico. Electronic address:

Published: March 2017

In this work we report on the hydrogen production capacity of single-chamber microbial electrohydrogenesis cell (MEC) with optimized design characteristics, in particular cathode surface area and anode-cathode spacing using acetate as substrate. The results showed that the maximal H production rates and best energetic performances could be obtained using the smallest, 71 cm stainless steel cathode and 4 cm electrode distances, employing a 60 cm bioanode. Cyclic voltammetric analysis was employed to investigate the dominant electron transfer mechanism of the architecturally optimized system.

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http://dx.doi.org/10.1016/j.chemosphere.2016.12.061DOI Listing

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