In this study, a bipolar membrane electrodialysis (BMED) process, which is thought to be an effective treatment method for leachate, was evaluated for leachates of three different ages ('young', 'middle-aged' and 'elderly'). The leachates were pretreated to eliminate membrane fouling problems prior to the BMED process. Experimental studies were carried out to determine optimal operating conditions for the three differently aged leachates in the BMED process. According to the experiment results, there was a high removal efficiency of conductivity determined at 4 membrane - 25 V for young and elderly leachate and at 1 membrane - 25 V for middle-aged leachate. It was found that the operating times required to reach the optimal endpoints (at conductivity of about 2 mS/cm) of BMED process were 90, 180 and 300 min for the middle-aged, young and elderly leachates, respectively. Under the optimum operating conditions for the BMED process, removal efficiencies of conductivity and chemical oxygen demand were determined to be 89.5% and 60% for young, 82.5% and 30% for middle-aged and 91.8% and 26% for elderly leachate, respectively.
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http://dx.doi.org/10.1080/09593330.2016.1276221 | DOI Listing |
J Environ Manage
January 2025
Dipartimento di Ingegneria, Università degli studi di Palermo, Viale delle Scienze ed. 6, 90128 Palermo, Italy.
Electrodialysis with Bipolar Membranes (EDBM) is an electro-membrane process that produces acid and base from saline solutions using electricity. In previous research, this technology has predominantly been explored at the laboratory scale, with very few examples at the pilot scale. This study investigated, for the first time, how differential pressures applied between the EDBM channels affect its performance, utilizing a semi-industrial scale pilot - the largest ever studied in the literature.
View Article and Find Full Text PDFChemosphere
October 2024
Department of Chemical Engineering, ProcESS-Process Engineering for Sustainable System, KU Leuven, Celestijnenlaan 200F, B-3001, Leuven, Belgium; Faculty of Engineering and the Built Environment, Tshwane University of Technology, Private Bag X680, Pretoria, 0001, South Africa.
Chromium electroplating produces Cr(III)-containing electroplating sludge (EPS) in large volumes, which is easily oxidised to Cr(Ⅵ) and is harmful to the environment and human health. This study recovered Cr(III) as NaCrO from EPS using an integrated bipolar membrane electrodialysis (BMED)-HO oxidation technology. During the treatment process, Cr(III) was oxidised to Cr(VI) using HO in an alkaline environment, BMED was used to separate and recover Cr(VI).
View Article and Find Full Text PDFJ Environ Manage
November 2024
State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, University of Chinese Academy of Sciences, Chinese Academy of Science, Beijing, 100085, China. Electronic address:
Water Res
October 2024
Key Laboratory of Reservoir Aquatic Environment, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714, China; Chongqing School, University of Chinese Academy of Science, Chongqing 400714, China.
The depletion of nutrient sources in fertilizers demands a paradigm shift in the treatment of nutrient-rich wastewater, such as urine, to enable efficient resource recovery and high-value conversion. This study presented an integrated bipolar membrane electrodialysis (BMED) and hollow fiber membrane (HFM) system for near-complete resource recovery and zero-discharge from urine treatment. Computational simulations and experimental validations demonstrated that a higher voltage (20 V) significantly enhanced energy utilization, while an optimal flow rate of 0.
View Article and Find Full Text PDFEnviron Technol
July 2024
Tianjin Key Laboratory of Water Quality Science and Technology, School of Environmental and Municipal Engineering, Tianjin Chengjian University, Tianjin, People's Republic of China.
Ammonia monohydrate (NH·HO) is an important chemical widely used in industrial, agricultural, and pharmaceutical fields. Reject water is used as the raw material in self-built bipolar membrane electrodialysis (BMED) to produce NH·HO. The effects of electrode materials, membrane stack structure, and operating conditions (current density, initial concentrations of the reject water, and initial volume ratio) on the BMED process were investigated, and the economic costs were analyzed.
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