Revolution from monometallic to trimetallic nanoparticle composites, various synthesis methods and their applications: A review.

Mater Sci Eng C Mater Biol Appl

School of Chemistry & Physics, University of KwaZulu-Natal, Pietermaritzburg Campus, Private Bag X01, Scottsville 3209, South Africa.

Published: February 2017

Trimetallic nanoparticles are mainly formed by the combination of three different metals. The trimetallic catalysts were considerably more professional than bimetallic one. The trimetallic and bimetallic nanoparticles are of enormous attention than that of monometallic in both technological and scientific view as in these nanoparticles the catalytic properties can be tailored better than that of in the single monometallic catalyst. The trimetallic nanoparticles have been synthesized by different methods such as microwave, selective catalytic reduction, micro-emulsion, co-precipitation and hydrothermal etc. The surfaces area of trimetallic nanoparticles is comparatively unstable and thus gets simply precipitated away from their solution and ultimately resulted in their reduced catalytic activity. By using stabilizers like block copolymers, organic ligands, surfactants and dendrimers the trimetallic nanoparticles can be stabilized. The nanocomposites of trimetallics have been synthesized with inorganic and organic compounds such as: carbon, graphene, gelatin, cellulose, starch, chitosan, alginate, collagen and AlO etc. Trimetallic nanoparticles are used as a catalyst due to their outstanding electrochemical catalytic activity in comparison with the monometallic or bimetallic nanoparticles.

Download full-text PDF

Source
http://dx.doi.org/10.1016/j.msec.2016.11.002DOI Listing

Publication Analysis

Top Keywords

trimetallic nanoparticles
20
trimetallic
8
nanoparticles
8
bimetallic nanoparticles
8
catalytic activity
8
revolution monometallic
4
monometallic trimetallic
4
trimetallic nanoparticle
4
nanoparticle composites
4
composites synthesis
4

Similar Publications

Heterogeneous catalysts have emerged as a potential key for closing the carbon cycle by converting carbon dioxide (CO) into value-added chemicals. In this work, we report a highly active and stable ceria (CeO)-based electronically tuned trimetallic catalyst for CO to CO conversion. A unique distribution of electron density between the defective ceria support and the trimetallic nanoparticles (of Ni, Cu, Zn) was established by creating the strong metal support interaction (SMSI) between them.

View Article and Find Full Text PDF

This study presents a novel electrochemical immunosensor for the detection of pepsinogen I, a potential biomarker for gastric cancer, based on a unique PdAgPt/MoSnanocomposite. The key innovation lies in the synergistic combination of trimetallic PdAgPt nanoparticles with MoSnanoflowers, which has not been previously reported for pepsinogen I detection. This hybrid material demonstrates exceptional electron transfer properties and a significantly larger electroactive surface area compared to conventional materials.

View Article and Find Full Text PDF

Polyol-Assisted Synthesis of Ni/Cu/Ag Trimetallic Nanoparticles for Nonlinear Optical Applications.

ACS Omega

November 2024

Nano and Functional Materials Lab (NFML), Department of Physics, Manipal Institute of Technology, Manipal Academy of Higher Education, Manipal 576104, Karnataka, India.

Trimetallic nanoparticles (TMNPs) have opened a broad spectrum of applications with a new class of materialistic combinations in several fields from electronics to medicinal and environmental applications. In this work, we report the synthesis and characterization of Ni/Cu/Ag TMNPs using the polyol method and their nonlinear optical (NLO) studies. A broad surface plasmon resonance (SPR) peak at 443 nm evidences the formation of the Ni/Cu/Ag TMNPs with a peak shift compared to their mono- or bimetallic counterparts.

View Article and Find Full Text PDF

An advanced hybrid nanocomposite based on different metals (copper, cobalt, and chromium) decorated with sustainable polysaccharides (gelatin, GLN, and hydroxyethyl cellulose, HEC) was developed. The composite reflects several advantages including a controlled particle size, particle size distribution, along with promising antimicrobial and anticancer activities. Topographical and elemental analyses were carried out using field-emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HR-TEM), and energy dispersive X-ray analysis (EDX), demonstrating the formation of trimetallic nanoparticles (NPs) possessing domain sizes of 169 nm and 102 nm assigned to the free nanocomposite (Fcomp) and loaded nanocomposite (Lcomp), respectively.

View Article and Find Full Text PDF

Synergic effect of Fe-Sn-Ag tri-metallic nanoparticles synthesized by a green chemistry method on their photocatalytic activity.

J Environ Manage

December 2024

Universidad Nacional Autónoma de México/Centro de Nanociencias y Nanotecnología, Carr. Tijuana-Ensenada km107, Ensenada, 22860, Baja California, Mexico.

Article Synopsis
  • This research introduces a new method for creating tri-metallic nanoparticles (TMNPs) using a green chemistry approach, utilizing an extract from the Crocus sativus plant for stabilization.
  • The characterization of the TMNPs showed they have a spherical shape with an average size of 13 nm and included various analytical techniques like FT-IR, XRD, and TEM.
  • The TMNPs demonstrated remarkable effectiveness in breaking down commercial dyes, achieving 100% degradation efficiency in just 90 minutes under sunlight or LED light, along with a high mineralization rate.
View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!