A structurally prearranged carbaporphyrin, 22-methyl-m-benziporphyrin, provided the perfect macrocyclic platform to form gold(III) 22-methyl-m-benziporphyrin, which facilitates the specific m-benzene ring contraction yielding gold(III) 21-methyl 21-carbaporphyrin with remarkably high yield.
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| http://dx.doi.org/10.1002/chem.201604458 | DOI Listing |
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