The title compound, [Fe(CHNO)Cl(CHOS)]·7CHOS·2HO, was isolated accidentally from an Fe-NiCl·6HO-H-TEA-DMSO system [where H is the product of the condensation between -nitro-salicyl-aldehyde and 2-amino-2-methyl-propane-1,3-diol and dimethyl sulfoxide (DMSO), and TEA is triethylamine]. The structure is based on a trinuclear {Fe(μ-O)} core, with an angular arrangement of the Fe ions that can be explained by the geometrical restrictions of two bulky ligands, each coordinating to all of the metal cations.
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| http://dx.doi.org/10.1107/S2056989016018508 | DOI Listing |
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