Crystal structure of -poly[di-ammonium [di-μ-oxalato-cuprate(II)]].

Acta Crystallogr E Crystallogr Commun

Department of Chemistry and Chemical Biology, MSC03 2060, 1 University of New Mexico, Albuquerque, NM 87131, USA; Advanced Materials Laboratory, Sandia National Laboratories, 1001 University Blvd SE, Albuquerque, NM 87106, USA.

Published: December 2016

The structure of the title compound, {(NH)[Cu(CO)]} , at 100 K has monoclinic (2/) symmetry with the Cu atom on an inversion center. The compound has a polymeric structure due to long Cu⋯O inter-actions which create [Cu(CO)] chains along the axis. The structure also displays inter-molecular N-H⋯O hydrogen bonding, which links these chains into a three-dimensional network.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137607PMC
http://dx.doi.org/10.1107/S2056989016017631DOI Listing

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